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Quote from: Lestat on November 30, 2013, 03:55:29 PMWondering if the Appel reaction can be run in chloroform, or even dichlor, rather than carbon tet, which has been declared anathema by the powers that be as a carcinogen, and is now about as hard to obtain via commercial suppliers as fossilized unicorn shit.Damn shame too, as its a very useful solvent for certain reactions, as it is very, very, very inert, even to some truly obnoxious, viciously reactive oxidizers, nasty ass fluorinated compounds etc. And is called for as a reagent, rather than solvent for the appel rxn (using CCl4 and triphenylphosphine to transform an alcohol to an alkyl halide. Nice mild rxn conditions..and I happen to have quite a lot of triphenylphosphine handy)I run across all sorts of old banned chemicals that used to be commonly used at estate sales including carbon tet. Mostly I leave it alone unless I have a use or I know I can sell it like freon.
Wondering if the Appel reaction can be run in chloroform, or even dichlor, rather than carbon tet, which has been declared anathema by the powers that be as a carcinogen, and is now about as hard to obtain via commercial suppliers as fossilized unicorn shit.Damn shame too, as its a very useful solvent for certain reactions, as it is very, very, very inert, even to some truly obnoxious, viciously reactive oxidizers, nasty ass fluorinated compounds etc. And is called for as a reagent, rather than solvent for the appel rxn (using CCl4 and triphenylphosphine to transform an alcohol to an alkyl halide. Nice mild rxn conditions..and I happen to have quite a lot of triphenylphosphine handy)
Quote from: couldbecousin on December 03, 2013, 06:25:55 PMQuote from: Lit on December 03, 2013, 08:42:55 AMI should get that new waitress. I'm sure she will give up her arsehole to someone unworthy NT without the slightest knowledge of Latin and Lysander Spooner You assume she would give up her arsehole. Maybe she is like me. Why did you write "arsehole"? You're an American.
Quote from: Lit on December 03, 2013, 08:42:55 AMI should get that new waitress. I'm sure she will give up her arsehole to someone unworthy NT without the slightest knowledge of Latin and Lysander Spooner You assume she would give up her arsehole. Maybe she is like me.
I should get that new waitress. I'm sure she will give up her arsehole to someone unworthy NT without the slightest knowledge of Latin and Lysander Spooner
I need more coffee.
Jesus died on the cross to show us that BDSM is a legitimate form of love.
There is only one truth and it is that people do have penises of different sizes and one of them is the longest.
I need to do something about my stress levels.
I need to do something about mine.
it is well known that PMS Elle is evil.
I think you'd fit in a 12" or at least a 16" firework mortar
You win this thread because that's most unsettling to even think about.
Quote from: odeon on December 02, 2013, 11:48:41 PMI need to do something about my stress levels.Quote from: hykeaswell on December 03, 2013, 02:04:04 AMI need to do something about mine. I need to do something about mine.
It's been a long week and I am really ready to go home!
I can do upside down chocolate moo things!
No more food porn.
Quote from: PMS Elle on December 05, 2013, 06:58:30 AMQuote from: odeon on December 02, 2013, 11:48:41 PMI need to do something about my stress levels.Quote from: hykeaswell on December 03, 2013, 02:04:04 AMI need to do something about mine. I need to do something about mine.Maybe the three of us need a long retreat. In a huge modernised castle, each in a separate wing.
